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Portrait of Princess Diana Diana Frances Spencer “Di” (1961-1997) Princess of Wales, UK. 1st wife to heir to UK Throne Prince Charles (Charles Philip Arthur George) (1948-living2013) Prince of Wales, UK. Diana is the 4th Child of Edward John "Johnnie" Spencer (1924-1992) 8th Earl Spencer UK & Frances Ruth Roche (Frances Ruth Spencer-Shand Kydd) (1936-2004) UK.